全文获取类型
收费全文 | 540篇 |
免费 | 43篇 |
国内免费 | 131篇 |
专业分类
安全科学 | 8篇 |
废物处理 | 10篇 |
环保管理 | 23篇 |
综合类 | 238篇 |
基础理论 | 94篇 |
污染及防治 | 161篇 |
评价与监测 | 178篇 |
社会与环境 | 2篇 |
出版年
2024年 | 1篇 |
2023年 | 2篇 |
2022年 | 16篇 |
2021年 | 12篇 |
2020年 | 12篇 |
2019年 | 24篇 |
2018年 | 12篇 |
2017年 | 18篇 |
2016年 | 38篇 |
2015年 | 25篇 |
2014年 | 40篇 |
2013年 | 89篇 |
2012年 | 43篇 |
2011年 | 62篇 |
2010年 | 35篇 |
2009年 | 49篇 |
2008年 | 25篇 |
2007年 | 24篇 |
2006年 | 26篇 |
2005年 | 23篇 |
2004年 | 15篇 |
2003年 | 16篇 |
2002年 | 22篇 |
2001年 | 14篇 |
2000年 | 15篇 |
1999年 | 12篇 |
1998年 | 10篇 |
1997年 | 8篇 |
1996年 | 5篇 |
1995年 | 5篇 |
1994年 | 3篇 |
1993年 | 4篇 |
1992年 | 4篇 |
1991年 | 1篇 |
1990年 | 3篇 |
1987年 | 1篇 |
排序方式: 共有714条查询结果,搜索用时 15 毫秒
71.
Mingming Lu Prabhat Lamichhane Fuyan Liang Eric Imerman Ming Chai 《Water, Air, & Soil Pollution: Focus》2008,8(3-4):359-367
The odorous air emissions from confined animal feeding operations (CAFOs), such as swine, poultry and dairy farms, are increasingly
raising community complaints. Odorous emissions can result in health damages, psychological discomforts and adverse aesthetic
effects in the community. However, these emissions are not well characterized up to now due to the lack of legislation, the
limitations in sampling and instrumentation techniques, and the complexity of the emissions themselves. This study is aimed
at the development of a high volume sampler and sorbent assembly to identify the odor causing compounds from a diary CAFO.
The sorbent was custom designed to target the potential compounds that may exist in a dairy farm and was validated in laboratory
with a synthetic odor from the swine manure. The actual samples at the diary farm were collected in spring and summer of 2005.
The sorbents were solvent extracted and individual odor compounds were identified using GC–MS (gas chromatography–mass spectroscopy).
The data obtained indicated that high volume sampling can shorten the sampling time from days to within 4 h. Both volatile
organic compounds (VOCs) and volatile fatty acids (VFAs) have been identified from the dairy farm, such as phenol, methylphenol,
4-ethyl phenol, indole, methyl indole, benzyl alcohol, hexanoic acid, valeric acid and iso-valeric acid, together with some nitrogen containing compounds that have not been reported before. 相似文献
72.
73.
74.
Municipal wastewater reclamation is becoming of increasing importance in the world to solve the problem of water scarcity. A better understanding of the molecular composition of effluent organic matter(Ef OM) in the treated effluents of municipal wastewater treatment plants(WWTPs) is crucial for ensuring the safety of water reuse. In this study, the molecular composition of Ef OM in the secondary effluent of a WWTP in Beijing and the reclaimed water further treated with a coagulation–sedimentation–ozonation process were characterized using a non-target Fourier transform ion cyclotron resonance mass spectrometry(FT-ICR MS) method and compared to that of natural organic matter(NOM) in the local source water from a reservoir. It was found that the molecular composition of Ef OM in the secondary effluent and reclaimed water was dominated by CHOS formulas, while NOM in the source water was dominated by CHO formulas. The CHO formulas of the three samples had similar origins. Anthropogenic surfactants were responsible for the CHOS formulas in Ef OM of the secondary effluent and were not well removed by the coagulation-sedimentation-ozonation treatment process adopted. 相似文献
75.
针对两种甲醛-DNA加合物,N~6-羟甲基腺嘌呤(N~6-HOMe-d A)和N2-羟甲基鸟嘌呤(N_2-HOMe-d G),本实验室建立了基于液相色谱串联质谱的分析方法,以便从DNA分子水平上探讨甲醛暴露对DNA的损伤作用机理,其中[~(15)N_5]N~6-Me-d A和[~(13)C_(10)~(15)N_5]N_2-Me-d G为内标;液相分离所用色谱柱为Thermo Polar Advantage II C_(18);方法的精密度较好(RSD5%)、灵敏度较高(检出限分别为0.014和0.0064 ng·m L~(-1))、回收率良好(94.9%~111%).后用小牛胸腺DNA进行体外染毒实验,设置甲醛染毒的浓度梯度(0.001,0.01,0.05,0.1,0.5和1 mmol·L~(-1))和染毒时间组(0、2、4、8、12、16、24 h),利用建立的LC-MS/MS方法检测了DNA中N~6-HOMe-d A和N_2-HOMe-d G的含量.结果表明,两种甲醛-DNA加合物N~6-HOMe-d A和N2-HOMe-d G的量与甲醛暴露存在剂量-反应和时间-反应关系. 相似文献
76.
采用液相色谱法对环境空气中的酰胺类化合物进行了测定,优化了实验条件.液相色谱采用C18柱,以水∶乙腈(93∶7)为流动相,流速为0.5 mL/min,柱温:30℃,紫外检测器波长198 nm.二甲基甲酰胺的检出限为0.006 3 mg/m3,三个不同浓度的加标回收率为95.0%~98.3%;二甲基乙酰胺的检出限为0.009 2 mg/m3,三个不同浓度的加标回收率为91.3%~98.2%;丙烯酰胺的检出限为0.004 9 mg/m3,三个不同浓度的加标回收率为96.3%~102%. 相似文献
77.
电感耦合等离子体质谱法在环境监测中的应用 总被引:2,自引:0,他引:2
针对ICP-MS技术的使用特点及其近年来在环境监测领域的应用进行综合阐述,并对ICP-MS技术的发展前景作出简单的评述。 相似文献
78.
The effect of hexadecyltrimethyleamine bromide (HDTMAB) on the removal of A lexandrium sp. LC3 under cupric glutamate stress was investigated. Toxic effect of cupric glutamate on A lexandrium sp. LC3 was significantly promoted in the presence of HDTMAB, especially at 3.0 cmc of HDTMAB. It was found that the sulfhydryl group content of the cell decreased, while the malonaldehyde content and membrane permeability increased when A lexandrium sp. LC3 was treated with HDTMAB and cupric glutamate complex, compared with cupric glutamate alone. The data suggest that HDTMAB might stimulate the damage of A lexandrium sp. LC3 by enhancing the membrane permeability. 相似文献
79.
磺酰脲类除草剂的残留分析 总被引:8,自引:0,他引:8
磺酰脲类除草剂是一类新型超高效除草剂,大约包括2V化合物,已被广泛用于禾谷作物防除阔叶杂草以及某些禾本科杂草,该类除草剂在环境中的残留浓度〈1μg.kg^-1水平。常规的分析方法包括生物鉴定,酶免疫分析,气相色谱法和高效液相色谱法(HPLC)、HPLC/MS联用后,可以准确测定复杂环境样中磺酰脲类除草剂的痕量残留。 相似文献
80.
泥沙对双酚A的吸附及其影响因素研究 总被引:5,自引:0,他引:5
以黄河泥沙为例,用SPE HPLC MS MS的方法分析了双酚A在泥沙上的吸附规律及其影响因素.结果表明,由于黄河泥沙碳酸盐含量较高,双酚A的等温吸附规律不能用线性吸附方程和Freundlich吸附方程来描述;去除泥沙中碳酸盐后,泥沙对双酚A的吸附量增加,且其吸附规律可用线性吸附方程和Freundlich吸附方程来描述.泥沙总有机质含量和可溶态有机质含量都会影响双酚A的吸附,沉积物和悬浮物对双酚A的吸附量分别与其可溶态有机质含量负相关;由于价态不同,钙离子和钾离子对双酚A的吸附影响规律相反,随着钙离子浓度的增加双酚A吸附量亦增加,而随着钾离子浓度的增加双酚A吸附量却减少. 相似文献